Civil Engineering MCQAE Level Civil Engineering

In breakpoint chlorination, the breakpoint is reached when:

Environmental EngineeringBreakpoint ChlorinationMEDIUM

Choose the correct answer

A

Chlorine first appears in treated water without any reaction

B

All ammonia nitrogen is oxidized to N2/nitrate and free chlorine residual begins to appear

C

The pH reaches 7.0

D

Coliform bacteria are first destroyed

Correct Answer

B. All ammonia nitrogen is oxidized to N2/nitrate and free chlorine residual begins to appear

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Breakpoint chlorination: as chlorine dose increases, it reacts with organics and ammonia. Combined chlorine (chloramines) increases then decreases (oxidation to N2). Breakpoint = minimum of the curve where all NH3 is oxidized; further addition gives free chlorine residual. Typical Cl2:NH3-N ratio = 7.6:1 at breakpoint.

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